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青金石(Lapis Lazuli) |
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美麗的青金石項鍊和耳環 |
作者:林豐田 GIC珠寶鑑定師資格證書
GIC翡翠鑑定師證書
本文也刊在這一期的台灣珠寶雜誌,中英文對照 ( 2008-8-26 )
青金石的原文名稱為Lapis Lazuli,來自拉丁語Lapis Lazuli,在中國古代稱為璆琳、金精、瑾瑜、青黛等。佛教稱為吠努離或璧琉璃,佛教界常使用之,其工藝品稱“青金”,古稱“金碧”、“點黛”或“璧琉璃”。
青金石早在6000年前即被中亞國家開發使用。中國則始於西漢時期,當時的名稱是“蘭赤”、“金螭”、“點黛”等。自明清以來,青金石“色相如天”,天為上,因此明清帝王重青金石。
好的青金石顏色深藍純正,無裂紋、質地細膩,無方解石雜質。不含金星(黃鐵礦)或帶有很漂亮的金星均為上品。世界上著名的青金石產地有阿富汗、智利、前蘇聯和加拿大等地。但首推阿富汗。阿國所產青金石有著均勻的深藍至天藍色,極細粒的隱晶結構中夾雜微量的黃鐵礦,使其在陽光照射之下精光生輝。青金石被阿拉伯穆斯林國家呼之為“瑰寶”。
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青金石手鐲 |
一、青金石的物理化學特性
青金石屬架狀結構矽酸鹽中的方鈉石族礦物,化學分子式為(Na,Ca)8(AlSiO4)6 (SO4,S,Cl)2。晶質集合體呈緻密塊狀、粒狀結構。顏色為深藍色、紫藍色、天藍色、綠藍色等。如果含較多的方解石時呈條紋狀白色,含黃鐵礦時就在藍底上呈顯黃色星點,玻璃光澤和蠟狀光澤,條痕淺藍色,半透明至不透明。折射率1.50左右,摩氏硬度5-6,一般青金石玉料比重2.7-2.9。解理不發育,斷口參差狀。在長波紫外光照射下發橙色點光,在短波紫外線照射下發綠或白色螢光。濾色鏡下呈淡紅色,遇鹽酸緩慢溶解。 |
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青金石花瓶 |
二、青金石的成因與產地
青金石是由接觸交代變質作用形成,主要賦存於矽酸鹽-鎂質矽卡岩中和鈣質矽卡岩中。
青金石主要是由天藍石、方鈉石、藍方石、黃鐵礦及方解石等多種礦物所組合而成的一種半寶石,青金石上的金色點狀物質其實就是黃鐵礦,而白色的雲霧狀結構就是方解石,在埃及和中東國家的古老飾品中常可見到青金石作成的飾品,甚至被埃及人認為是一種聖石。
由於組成礦物的比例不同,青金石的顏色與紋理都會有些許差異,青金石的本體藍由於產地不同而呈深淺不一的色調,主要由組成的藍色礦物與白色方解石所佔的比例而定,其上的紋理則有由黃鐵礦(Pyrite)形成的金黃色斑點或由白色方解石(Calcite)形成的白色紋路,一般而言,上等的青金石的本體色呈適中而飽和的藍色,而同時以其上具金色斑點者較受人喜愛。
青金石的主要產地有阿富汗、美國、蒙古、緬甸、智利、加拿大、巴基斯坦、印度和安哥拉等國。中國大陸至今未發現青金石礦床。
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青金石的結構 |
三、青金石與相似玉石的區別
與青金石容易混淆的有方鈉石、藍方石、藍銅礦。冒充青金石的贗品和代用品有著色碧玉、著色尖晶石、著色岫玉、料仿青金、染色大理石。
相似玉石特徵如下:
方鈉石(又稱蘇打石),呈粗晶質結構,顏色均一,硬度5.5-6,比重2.15-2.35,折射率1.483-1.487,質地不如青金石均勻,有橙色和粉紅色螢光。
藍方石,橙紅色螢光,比重2.44-2.50,折射率1.496-1.504。
藍銅礦,硬度小,為3.5-4,折射率1.73-1.83,雙折射率 : 0.108,性脆,無大的緻密塊體。
著色碧玉(又稱瑞士青金),用玉髓或碧玉等假料人工著色而成,硬度大,為6.5-7,折射率1.53-1.55,比重:2.6。
著色尖晶石(又稱著色青金),用鈷鹽人工著色而成,硬度大,為8,折射率1.71-1.73。
著色岫玉(又稱熗色青金),淺藍色,見不到黃鐵礦,油脂光澤強,硬度4.8-5.5,折射率1.56-1.57,比重2.54-2.84。
料仿青金,用玻璃仿造,由著色的深藍色硫磺或玻璃構成的,見不到黃鐵礦,玻璃光澤,貝殼狀斷口,性脆。染色大理岩,硬度小,小刀容易刻動,遇鹽酸反應明顯。 |
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Gilson公司合成的人工青金石 |
四、青金石的評價與選購
青金石在選擇上以色澤均勻無裂紋,質地細膩有漂亮的金星為佳,如果黃鐵礦含量較低,在表面不出現金星也不影響品質。但是如果金星色澤發黑、發暗,或者方解石含量過多在表面形成大面積的白斑,則價值大大降低。 |
Lapis Lazuli
中譯英:林嵩暉(GIC珠寶鑑定師資格證書、GIC翡翠鑑定師證書)
Lapis lazuli , from Latin name “ Lapis Lazuli”, in ancient China it called as “ Qiulin” , ” Jinjing ”, “ Jinyu ”, “ Qingdai ” etc. (transliteration,means “beautiful jade”). Buddhist named it as “Feinuli”, “ Biliuli ” , which ofen applicated in Buddhist activity. The workmanship also named “Qingjing”,and named “Jingbi”,”Diandai”,or “Biliuli” in ancient China. (transliteration,means “precious jade”).
Lapis lazuli was exploited by the Middle Asian people since 6000 years ago. It was also applicated in the Western Han Dynasty of China, named “Lanchi”, “ Jingli ”,or “ Diandai”,etc. (transliteration, “precious gemstone”). Since the Ming and Qing Dynasty ,most Chinese monarches like Lapis lazuli because of its color and looks, that like heaven. Heaven is the great, so these monarches set store by it.
Good lapis lazuli displays ultramarine and purity, no crackle, fine and smooth quality , and no obvious calcite inside. These are all good lapis no matter what contain pyrite inside or not. There are famous lazuli producing area in Afghanistan, Chile, the former Soviet Union, and Canada ,but product from Afghanistan is the best one. Afghanistan’s product is even, from sky blue to ultramarine color. Because its small cryptocrystalline texture mixed up with minute pyrite inside , lazuli shows glittering below sunshine. Meanwhile, Lapis lazuli is the treasure of Arab Moslem country .
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Physical and chemical characteristics of lapis lazuli
Lapis lazuli belongs to sodalite group of tectosilicate mineral, molecular formula: (Na, Ca) 8 (AlSiO4) 6 (SO4, S, Cl) 2 . Crystal aggregation body appears dense lump, graininess structure with dark blue, indigo, sky blue, or turquoise color. If lazuli contains much calcite inside , it will appears stripy white.,If pyrite, it will display yellow spots in blue background.
Characteristics: glass or wax luster, striation with Cambridge blue color, half transparency to not clear, refractive index about 1.50 . Mohs’ scale of hardness: 5-6 , ordinary lapis lazuli :S.G.2.7-2.9, cleavage: unruly , fracture :irregular, long wave ultraviolet light : orange fluorescence , shortwave ultraviolet ray : green or white fluorescence , CCF: rosiness color , in hydrochloric acid : slow dissolution. |
Formation and production of Lapis lazuli
Lapis lazuli is formed by hydrothermal contact metamorphism, mostly in silicate-magnesium skarn and calcium skarn . Lazuli is mainly composed of lazulite , sodalite, haüynite, pyrite, and calcite, so that it’s a kind of semi-precious stone.
Lapis lazuli has the “ golden spots” on the surface ,that is pyrite ,and the white cloudy material is calcite . In Egypt and Middle East ,the ancient decorations often were made of lapis lazuli , furthermore that it was a kind of saint stone in Egypt.
Because of different ratio of components, lapis lazuli has different color and texture . Different products display different blue because of the ratio of blue mineral and white calcite. Golden spots are formed by pyrite , and white grains are formed by white calcite . Generally , first-class lazuli noumenon displays moderate and saturated blue , and meantime is favorable to most people.
Lapis lazuli chief produced in Afghanistan , America, Mongolia, Myanmar, Chile, Canada, Pakistan, India and Angola etc. ,but mainland China not yet found.
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Lapis lazuli and simulants
The minerals easy to cofuse with lazuli are sodalite, haüynite , azurite . The simulants and substitutes are dyed jasper (Swiss lapis) , dyed spinel , dyed Xiuyan jade, imitated lazuli, and dyed marble etc..
The characteristics of simulants as follows:
Sodalite : rough grain structure, even color, hardness 5.5-6, S.G. 2.15-2.35, refractive index 1.483-1.487, texture is not as good as lazuli, and there are orange and carnation fluorescence.
Haüynite : salmon pink fluorescence, S.G.:2.44-2.50, refractive index 1.496-1.504.
Azurite : small hardness: 3.5-4, refractive index :1.73-1.83, DR : 0.108 , fragile, no obvious big dense lump.
Dyed jasper (Swiss lapis) : dyed chalcedony, dyed jasper etc. , hardness : 6.5-7, refractive index 1.53-1.55, S.G.:2.6.
Dyed spinel : cobalt manpower colored up, hardness: 8, refractive index 1.71-1.73.
Dyed Xiuyan jade : Cambridge blue , no obvious pyrite, strong grease luster, hardness 4.8-5.5 , refractive index 1.56-1.57, S.G.:2.54-2.84.
Imitated lazuli: glass mimic, composed of dyed ultramarine sulfur or glass, no pyrite inside, glass luster, conchoidal fracture, fragile.
Or, dyed marble , small hardness, knife easy to carve , obvious reaction in hydrochloric acid .
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Valuation and purchase of lapis lazuli
Good lapis lazuli has even color and luster ,no obvious flaw, fine and smooth texture with beautiful golden spots. If pyrite component is low, it will not affect its quality ,and If golden spots are too dark, or calcite content too much, so as to form large white spots on the surface, then the valuation will obviously play down. |
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